Changes in annual temperature extremes in the Carpathians since AD 1961

The Carpathian Mountains region cover areas from seven countries of central and southeastern Europe, the mountain chain having major regional influences on the temperate climate, specific to latitudes between 43°N and 49°N. In order to identify changes in the annual temperature extremes, the Mann–Kendall nonparametric trend test has been applied to several thermal indices, recommended by the expert team on climate change detection and indices. The indices were computed from gridded daily datasets of minimum and maximum temperature at 0.1° resolution (~10 km), available online within the framework of the project CarpatClim (climate of the Carpathian region) for the period 1961–2010. The results show decreasing trends in cold-related indices, especially in the number of frost days, and increasing trends in warm-related ones. The trend patterns are consistent over the region, i.e., there are no mixed trends for a given index. Regional differences in climate extreme trends within the Carpathian region are related to altitude, rather than latitude. The number of summer days is increasing over the entire area, while the number of tropical nights presents upward trends mainly at lower elevations. The Warm Spell Duration Index presents upward trends over 60 % of the region. The (annual) East Atlantic pattern shows strong correlations with the warm-related indices. Our results are in agreement with previous temperature-related studies in the region.     

Improved reliability of ENSO hindcasts with multi-ocean analyses ensemble initialization

Currently, ensemble seasonal forecasts using a single model with multiple perturbed initial conditions generally suffer from an “overconfidence” problem, i.e., the ensemble evolves such that the spread among members is small, compared to the magnitude of the mean error. This has motivated the use of a multi-model ensemble (MME), a technique that aims at sampling the structural uncertainty in the forecasting system. Here we investigate how the structural uncertainty in the ocean initial conditions impacts the reliability in seasonal forecasts, by using a new ensemble generation method to be referred to as the multiple-ocean analysis ensemble (MAE) initialization. In the MAE method, multiple ocean analyses are used to build an ensemble of ocean initial states, thus sampling structural uncertainties in oceanic initial conditions (OIC) originating from errors in the ocean model, the forcing flux, and the measurements, especially in areas and times of insufficient observations, as well as from the dependence on data assimilation methods. The merit of MAE initialization is demonstrated by the improved El Niño and the Southern Oscillation (ENSO) forecasting reliability. In particular, compared with the atmospheric perturbation or lagged ensemble approaches, the MAE initialization more effectively enhances ensemble dispersion in ENSO forecasting. A quantitative probabilistic measure of reliability also indicates that the MAE method performs better in forecasting all three (warm, neutral and cold) categories of ENSO events. In addition to improving seasonal forecasts, the MAE strategy may be used to identify the characteristics of the current structural uncertainty and as guidance for improving the observational network and assimilation strategy. Moreover, although the MAE method is not expected to totally correct the overconfidence of seasonal forecasts, our results demonstrate that OIC uncertainty is one of the major sources of forecast overconfidence, and suggest that the MAE is an essential component of an MME system.     

A critical zone observatory dedicated to suspended sediment transport: The meso-scale Galabre catchment (southern French Alps)

The 20 km² Galabre catchment belongs to the French network of critical zone observatories (OZCAR; Gaillardet et al., Vadose Zone Journal, 2018, 17(1), 1–24). It is representative of the sedimentary lithology and meteorological forcing found in Mediterranean and mountainous areas. Due to the presence of highly erodible and sloping badlands on various lithologies, the site was instrumented in 2007 to understand the dynamics of suspended sediments (SS) in such areas. Two meteorological stations including measurements of air temperature, wind speed and direction, air moisture, rainfall intensity, raindrop size and velocity distribution were installed both in the upper and lower part of the catchment. At the catchment outlet, a gauging station records the water level, temperature and turbidity (10 min time-step). Stream water samples are collected automatically to estimate SS concentration-turbidity relationships, allowing quantification of SS fluxes with known uncertainty. The sediment samples are further characterized by measuring their particle size distributions and by applying a low-cost sediment fingerprinting approach using spectrocolorimetric tracers. Thus, the contributions of badlands located on different lithologies to total SS flux are quantified at a high temporal resolution, providing the opportunity to better analyse the links between meteorological forcing variability and watershed hydrosedimentary response. The set of measurements was extended to the dissolved phase in 2017. Both stream water electrical conductivity and major ion concentrations are measured each week and every 3 h during storm events. This extension of measurements to the dissolved phase will allow progress in understanding both the origin of the water during the events and the partitioning between particulate and dissolved fluxes of solutes in the critical zone. All data sets are available at https://doi.osug.fr/public/DRAIXBLEONE_GAL/index.html .     

Lidar observations of volcanic dust over Polish Polar Station at Hornsund after eruptions of Eyjafjallajökull and Grímsvötn

Two significant volcanic eruptions, i.e., Eyjafjallajökull (April–May 2010) and Grímsvötn (May 2011) took place recently in Iceland. Within a few days after eruptions, layers of high aerosol concentration have been observed by multiwavelength lidar of the Polish Polar Station at Hornsund, Svalbard. Measurements of the aerosol’s optical properties indicated a possible presence of volcanic ash transported over the Station. The latter presumption was confirmed by the computed backward trajectories of air masses, showing their paths passing over the location of volcanoes.     

Modelling colloid association with plutonium: The effect of pH and redox potential

An analytical expression that evaluates the effect of pH and the redox potential (E) on Pu-colloid association was studied on a model basis. It includes surface complexation with one type of surface site and its formulation leads to a distribution coefficient (K_d) as a function of the pH (hydrolysis) and E (redox sensitive species). The formulation also considers the values of the stability and hydrolysis constants for all species present in solution and associated at the surface. Correlations between hydrolysis and surface complexation constants reported in the literature have been applied systematically to evaluate sorption of all species for each colloid system. The presence of ligands in solution was also taken into account. The model was applied to study the association of Pu onto colloids coated with AlOH, FeOH or SiOH groups in the presence and in the absence of carbonates in solution. The tests performed with the model suggest that the oxidation of Pu(III) to Pu(IV) has the potential to increase sorption, as demonstrated by the increased K_d values. Under natural conditions Pu may be present at oxidation states of (III)--(VI), and the effect of redox potential is significant because of the differences in the sorption of each oxidation state. When carbonates are present in the solution, the calculated values of distribution coefficient were lower than those calculated in the absence of carbonates, particularly in the case of Pu(VI). The K_d values obtained with the developed model are compared with experimental values reported for the sorption of Pu onto colloids. This model can equally be applied to study the sorption of other redox sensitive elements.     

The Seashell Wastes as Biosorbent for Reactive Dye Removal from Textile Effluents

This study investigates structural and adsorption properties of the powdered waste shells of Rapana gastropod and their use as a new cheap adsorbent to remove reactive dye Brilliant Red HE‐3B from aqueous solutions under batch conditions. For the powder shells characterization, solubility tests in acidic solutions and X‐ray diffraction (XRD), scanning electron microscopy (SEM), energy‐dispersive X‐ray spectroscopy (EDX), Fourier transform IR spectroscopy (FT‐IR) and thermogravimetric analyses were performed. The results revealed that the adsorbent surface is heterogeneous consisting mainly from calcium carbonate layers (either calcite or aragonite) and a small amount of organic macromolecules (proteins and polysaccharides). The dye adsorptive potential of gastropod shells powder was evaluated as function of initial solution pH (1–5), adsorbent dose (6–40 g L^?1), dye concentration (50–300 mg L^?1), temperature (5–60°C), and contact time (0–24 h). It was observed that the maximum values of dye percentage removal were obtained at the initial pH of solution 1.2, shells dose of 40 g L^?1, dye initial concentration of 50–50 mg L^?1 and higher temperatures; the equilibrium time decreases with increasing of dye concentration. It is proved that the waste seashell powder can be used as low cost bioinorganic adsorbent for dyes removal from textile wastewaters.     

The study on highly expressed proteins as a function of an elevated ultraviolet radiation in the copepod, Tigriopus japonicus

The objective of the study was to analyze constantlyhighly expressed proteins as a function of elevated midultraviolet (UVB, 280?C315 nm) radiation in Tigriopus japonicus sensu lato (T. japonicus s.l). We also analyzed associations between kinetics of radiation avoidance, measured as a covered distance per time unit, and highly expressed proteins. The obtained results indicate an increase in T. japonicus s.l. mobility between the control (no radiation) and mild UV radiation levels (15 kJ·m^?2). Two-dimensional gel electrophoresis combined with MALDI-MS-MS resulted in 2D protein map comprising of 686 protein spots, of which 19 were identified as highly expressed proteins across all experimental conditions. Obtained results indicate that calpain, vitellogenin, and collagenase are housekeeping protein that are expressed at a constant level independently of environmental changes and that adoption of a locomotive system for the avoidance of a UV source may be, at least partially, supported by hepatopancreas-driven metabolism.     

Labile and stabile soil organic carbon fractions in surface horizons of mountain soils–relationships with vegetation and altitude

Global and local climate changes could disturb carbon sequestration and carbon stocks in forest soils. Thus, it is important to characterize the stability of soil organic matter and the dynamics of soil organic carbon (SOC) fractions in forest ecosystems. This study had two aims: (1) to evaluate the effects of altitude and vegetation on the content of labile and stabile forms of organic carbon in the mountain soils; and (2) to assess the impact of the properties of soil organic matter on the SOC pools under changing environmental conditions. The studies were conducted in the Karkonosze Mountains (SW Poland, Central Europe). The content of the most labile fraction of carbon (dissolved organic carbon, DOC) decreases with altitude, but the content of fulvic acids (FA), clearly increases in the zone above 1000 m asl, while the stabile fraction (humins, non-hydrolyzing carbon) significantly decreases. A higher contribution of stabile forms was found in soils under coniferous forests (Norway spruce), while a smaller - under deciduous forests (European beech) and on grasslands. The expected climate change and the ongoing land use transformations in the zone above 1000 m asl may lead to a substantial increase in the stable humus fraction (mainly of a non-hydrolyzing carbon) and an increase in the SOC pools, even if humus acids are characterized by a lower maturity and greater mobility favorable to soil podzolization. In the lower zone (below 1000 m asl), a decrease in the most stable humus forms can be expected, accompanied by an increase of DOC contribution, which will result in a reduction in SOC pools. Overall, the expected prevailing (spatial) effect is a decreasing contribution of the most stable humus fractions, which will be associated with a reduction in the SOC pools in medium-high mountains of temperate zone of Central Europe.     

Aerosol removal coefficients based on 7Be, 210Pb,and 210Po radionuclides in the urban atmosphere

Journal of Atmospheric Chemistry - In this study, the aerosol removal coefficients based on 7Be, 210Pb and 210Po radionuclides in the urban air, in Lodz, Poland, were investigated over 3 years,...